Developmentstatusofhigh-efficiencyHITsolarcells-solarbe文库

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Development status of high-efciency HIT solar cellsTakahiro Mishima n , Mikio Taguchi, Hitoshi Sakata, Eiji MaruyamaAdvanced Energy Research Center, SANYO Electric Co., Ltd., Japan, 7-3-2 Ibukidai-higashimachi, Nishi-ku, Kobe City, Hyogo 651-2242, Japana r t i c l e i n f oAvailable online 28 April 2010KeywordsHigh-efciency solar cellCrystalline siliconHeterojunctiona b s t r a c tThis paper describes the development status of high-efciency heterojunction with intrinsic thin-layerHIT solar cells at SANYO Electric. Presently, the conversion efciency of our standard HIT solar cell hasreached a level of 23.0 for a practical size of 100.4 cm 2 substrate. On the other hand, we havedeveloped special technologies for effectively using thinner substrates for HIT solar cells. Surprisingly,we have achieved a quite high open circuit voltage Voc of 743 mV, and a high conversion efciency of22.8 using only a 98- mm-thick substrate. A 98- mm-thick cell also exhibits a good temperaturecoefcient, and allows the thickness of the substrate to be reduced by more than 50 while maintainingits efciency. These results suggest that the HIT solar cell has the potential to further improvecost-performance.b effectively use thinner substrates;c improve the temperature coefcient of efciency;d develop a bifacial module.Some of the above points are related to special features of theHIT solar cell, such as its ability to use thinner substrates and itssymmetrical device structure.We have recently succeeded in raising the maximum conver-sion efciency for a practical sized standard HIT solar cell to23.0, measured at National Institute of Advanced IndustrialScience and Technology AIST Japan [1] , which was achieved byoptimizing a variety of processes at our laboratory [1] . Now, wehave set our new target for conversion efciency to 25.0. In thispaper, recent SANYO Electric activities for reducing the cost of theHIT solar cell will be described.2. High-efciency HIT solar cell2.1. HIT solar cell structureThe structure of the HIT solar cell is shown in Fig. 1 . Anintrinsic amorphous-Si layer, a doped amorphous-Si layer, and aTCO layer are deposited on both sides of a crystalline-Si substrate.Grid electrodes are also fabricated on both sides of the dopedamorphous-Si layer. Therefore, the HIT solar cell has asymmetrical structure, and does not use high-hardness alloymetals as electrodes. As a result, it achieves a stress-free cellstructure, which is well suited to thinner-substrate solar cells.The HIT solar cell uses high-quality and very-thin amorphoussilicon a-Si layers to form the Hetero-Junction. In addition, ahigh-quality intrinsic a-Si layer can effectively passivate thesurface dangling bonds of the crystalline silicon substrate. As aresult, this cell has achieved a high Voc of more than 700 mV [2] .Further, all of the process temperatures for HIT solar cells arebelow 200 1C, which allows it to preserve the initial high-levelquality of the crystalline silicon substrate. We have improved thea-Si/c-Si hetero-interface structure of the HIT solar cell throughfurther process optimization, to reach a Voc of more than720 mV [3] . The higher V oc offers not only a high conversionefciency but also a better temperature coefcient, which iscomparable to amorphous silicon solar cells Fig. 2 . Of course, abetter temperature coefcient of conversion efciency improvesthe output power under high temperature operating conditions.The symmetrical structure of the HIT solar cell is alsosuitable for bifacial modules, which are explained in detail [4]in Section 4.Contents lists available at ScienceDirectjournal homepage www.elsevier.com/locate/solmatSolar Energy Materials fax 81 78 993 1096.E-mail address takahiro.mishimasanyo.com T. Mishima.Solar Energy Materials Solar Cells 95 2011 18– 212.2. 23.0 Standard HIT solar cellPresently, the conversion efciency of the standard HIT solarcell has reached a level of 23.0 for a 100.4 cm 2 practical sizecrystalline silicon substrate Voc 729 mV, short circuit currentJsc 39.52 mA/cm 2 , ll factor 80.0. There are three keytechnologies for improving the conversion efciency of HIT solarcells. The rst point is to improve the HIT structure, which isrelated to improvement of heterojunction. The second point is tooptimize the grid electrode. And the third point is to improve theoptical connement structure, which is related to light absorptionin the cell [5] .2.3. Loss analysis of the 23.0 cellAiming for even higher efciency, we have analyzed variouslosses of the 23.0 HIT solar cell from experimental data EQE,IQE, reection spectra, etc.. From this analysis, the total powerloss is more than 20 percent of the current output power. Amongthe estimated losses, the loss by light reection and transmittanceaccounts for about 1/3. The light absorption loss in the TCO anda-Si, and the carrier recombination loss also account for about 1/3.And the remaining 1/3 consists of losses by the electrode shadeand series resistance.The majority of the power loss is related to the loss of incidentlight, and carrier recombination in the cell. Therefore, we willcontinue to make better components for e. g., TCO, a-Si, etc. forthe HIT solar cell. If we can lower these losses in the future, wewill be able to improve the conversion efciency.3. Thinner-substrate HIT solar cell3.1. Unique Voc propertyIn conventional cells, the output power generally decreaseswhen the cell thickness is reduced. This is mainly due to alowering of the Isc because of less light absorption, and due to alowering of the V oc caused by the surface recombination loss thatbecomes predominant in the total recombination loss of the solarcell. As a result, the output power decreases with cell thinning.However, high-performance HIT solar cells have differentcharacteristics. Fig. 3 shows the thickness dependence of HITsolar cell output parameters in RD. In Fig. 3, the Isc decreaseswith cell thinning, but the V oc increases with cell thinning. Weattribute these phenomena as follows. Total recombinationvelocity was determined only by bulk recombination due toextremely low surface recombination velocity of the HIT solarcells [6] . This makes it possible to maintain higher conversionefciency in the cell thickness region below 100 mm.3.2. New technologies for thinner cellsWe have customized our high-efciency technologies toimprove thinner-substrate HIT solar cells. There are two keytechnologies. The rst technology is related to a higher V oc. Itconsists of a new device design to obtain a higher Voc , and animproved junction formation process. This technology directlyimproves the diode characteristics of the HIT junction. The secondtechnology is related to a higher Jsc . We have optimized thetexture structure specially for thinner substrates, which leads toimproved optical connement. We have also reduced the opticalabsorption loss of the a-Si and TCO by using wide-gap a-Si lmsand high transparency TCO. As a result, a relatively high Jsc wasobtained with thinner substrates.Fig. 4 shows the optimized IQE spectra of HIT solar celloptimized for thinner-substrate cells. Here, the upper curveindicates the data of our newly developed cell, and the lowercurve indicates the data of a typical cell. In Fig. 4 , the shortwavelength response is improved by using a newly developed a-Silm, and the long wavelength response is related to a new TCOand improved texture structure.i-type a-Si 0.01 μ m c-Si CZ, n-type Grid electrode n-type a-Si 0.01 μ m TCO p-type a-Si 0.01 μ m Fig. 1. Structure of a HIT solar cell.Fig. 2. Temperature coefcient of the conversion efciency of HIT solar cells.Fig. 3. Thickness dependence of HIT Isc, Voc , Eff..Fig. 4. IQE spectra of improved HIT solar cell with new a-Si, new TCO, and texturestructure optimized for a thinner-substrate. Upper curve.T. Mishima et al. / Solar Energy Materials Solar Cells 95 2011 18– 21 193.3. 22.8 Thin 98 mm cellBy applying newly developed technologies for thinner-substrate HIT solar cells, we have obtained a conversion efciencyof 22.8 and a V oc of 743 mV for a 98- mm-thick practical size cellFig. 5 , certied by AIST. Other cell parameters are Jsc 38.84mA/cm 2 , ll factor 79.1, and cell size 100.3 cm 2. In particular,the Voc value of 743 mV is quite high for a crystalline silicon solarcell. Our new technologies enable us to obtain a higher Voc withthinner crystalline silicon substrates. A higher Voc also maintainsrelatively high conversion efciency with a thin substrate.Additionally, we have conrmed very low o 0.3/ 1Ctemperature coefcient of conversion efciency for 98 mm cell.3.4. Conversion efciency comparisonFig. 6 shows the history of conversion efciency for HIT solar cellsat our laboratory. During the last few years, we have accelerated theimprovement of the conversion efciency. At the same time, wehave started developing high-efciency thinner-substrate HIT solarcells, which today have reached an efciency of 22.8. Surprisingly,this 22.8 is comparable to our standard cell ’s best efciency of23.0. Indeed, our thinner HIT solar cell can reduce the thickness ofthe substrate by more than 50 while maintaining its efciency. Webelieve this will prove the possibility of further improving the cost-performance of HIT solar cells.4. HIT Double bifacial PV moduleThe HIT Double module uses the symmetrical structure featureof the HIT solar cell. This feature makes it possible to create abifacial module. Fig. 7 shows the normalized output power of HITDouble and single-sided HIT modules. The output power of theHIT Double is higher than that of the single-sided HIT modulethroughout the year. In this case, the HIT Double produces 10.9more output power than the single-sided HIT module. We believethe HIT Double module is proof of another possibility forimproving the performance of HIT solar cells.5. SummaryWe have achieved ofcially certied world ’s highest conver-sion efciency of 23.0 for a practical size 100.4 cm 2 crystallinesilicon solar cell [1,7] . In addition, we have conrmed thepotential of the HIT solar cell for thinner-substrate use byobtaining a conversion efciency of 22.8 and a Voc of 743 mVFig. 5. I– V characteristics of the 22.8 efciency HIT solar cell with 98- mm-thick substrate. Certied by AIST.Fig. 6. History of the HIT cell ’s conversion efciency RD.Fig. 7. Output power trends of single-sided HIT and bifacial HIT Double TMmodules throughout the year.T. Mishima et al. / Solar Energy Materials Solar Cells 95 2011 18– 2120for a 98- mm-thick cell. Indeed, the increased Voc successfullycompensates for the decreased Jsc in thinner-substrate HIT solarcells. Our thinner cells offer the advantage of not only a higher Vocbut also a better temperature coefcient. This suggests that theHIT solar cell has the potential of an improved overall perfor-mance in the near future. The HIT Double module can boost theoutput power by more than 10 over the single-sided HIT moduleby using a bifacial structure. We believe that all of these effortswill be linked to the further improvement of HIT solar cells.Acknowledgements‘‘ HIT’’and ‘‘ HITDouble ’’ are trademarks of SANYO Electric Co., Ltd.References[1] Mikio Taguchi, Yasufumi Tsunomura, Hirotada Inoue, Shigeharu Taira,Takeshi Nakashima, Toshiaki Baba, Hitoshi Sakata, Eiji Maruyama, High-efciency HIT solar cell on thin o 100 mm silicon wafer, in Proceedingsof the 24th European Photovoltaic Solar Energy Conference, 2009,pp. 1690– 1693.[2] M. Taguchi, M. Tanaka, T. Matsuyama, T. Matsuoka, S. Tsuda, S. 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Kuwano, Improvement of the conversion efciency of polycrystallinesilicon thin lm solar cell, Technical Digest of the Fifth InternationalPhotovoltaic Science and Engineering Conference, 1990, pp. 689– 692.[3] Yasufumi Tsunomura, Yukihiro Yoshimine, Mikio Taguchi, Toshiaki Baba,Toshihiro Kinoshita, Hiroshi Kanno, Hitoshi Sakata, Eiji Maruyama, MakotoTanaka, Twenty-two percent efciency HIT solar cell, Solar Energy Materialsand Solar Cells 93 2009 670– 673.[4] Hitoshi Sakata, Takuo Nakai, Toshiaki Baba, Mikio Taguchi, Sadaji Tsuge,Kenji Uchihashi, Seiichi Kiyama, 20.7 HIGHEST EFFICIENCY LARGE AREA100.5 cm 2 HIT TM CELL, in Proceedings of the 28th IEEE PhotovoltaicSpecialists Conference, 2000, pp. 7– 12.[5] Hiroshi Kanno, Daisuke Ide, Yasufumi Tsunomura, Shigeharu Taira, ToshiakiBaba, Yukihiro Yoshimine, Mikio Taguchi, Toshihiro Kinoshita, Hitoshi Sakata,Eiji Maruyama, Over 22 efcient HIT solar cell, in Proceedings of the 23rdEuropean Photovoltaic Solar Energy Conference, 2008, pp. 1136– 1139.[6] Hirotada Inoue, Yasufumi Tsunomura, Daisuke Fujishima, Ayumu Yano,Shigeharu Taira, Yasuko Ishikawa, Takeshi Nishiwaki, Takeshi Nakashima,Toshio Asaumi, Mikio Taguchi, Hitoshi Sakata, Eiji Maruyama, Improving theconversion efciency and decreasing the thickness of the HIT solar cell,Presented at the 2009 MRS Fall Meeting, in press.[7] Martin A. Green, Keith Emery, Yoshihiro Hishikawa, Wilhelm Warta, Solar cellefciency tables Version 34, Progress in Photovoltaics Research andApplications 17 2009 320– 326.T. Mishima et al. / Solar Energy Materials Solar Cells 95 2011 18– 21 21